Multiple Injection Method for Bulk Syndiospecific Polymerization of Styrene with Homogeneous Metallocene Catalyst
نویسندگان
چکیده
منابع مشابه
Kinetics and Morphology of Metallocene Catalyzed Syndiospecific Polymerization of Styrene in Homogeneous and Heterogeneous Reaction Systems
Title of Document: KINETICS AND MORPHOLOGY OF METALLOCENE CATALYZED SYNDIOSPECIFIC POLYMERIZATION OF STYRENE IN HOMOGENEOUS AND HETEROGENEOUS REACTION SYSTEMS Joong Jin Han, Doctor of Philosophy, 2008 Directed By: Professor Kyu Yong Choi Department of Chemical and Biomolecular Engineering Syndiotactic polystyrene (sPS) is a semicrystalline thermoplastic polymer with many advantageous properties...
متن کاملGroup (IV) Metallocene Complexes with Bulky ω-aryloxyalkyl-Substituted Indenyl Ligands as Catalyst Precursors for Homogeneous Ethylene Polymerization
A series of seven new complexes of zirconium and hafnium with bulky ω-aryloxyalkyl substituted indenyl ligands were synthesized and characterized by NMR spectroscopy and elemental analysis. These complexes were activated with methylaluminoxane and tested for homogeneous ethylene polymerization. The zirconium catalysts showed higher activities than their hafnium an...
متن کاملEffect of “Topotactic” Reduction Products on Catalytic Activity of Metallocene Catalyst for Olefin Polymerization
s of Doctor’s Thesises Effect of “Topotactic” Reduction Products on Catalytic Activity of Metallocene Catalyst for Olefin Polymerization Satoru Yamada † (Department of Chemistry for Materials)
متن کاملA Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization
A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.
متن کاملSimulation, Optimization & Control of Styrene Bulk Polymerization in a Tubular Reactor
In this paper, optimization and control of a tubular reactor for thermal bulk post-polymerization of styrene have been investigated. By using the reactor mathematical model, static and dynamic simulations are carried out. Based on an objective function including polymer conversion and polydispersity, reactor optimal temperature profile has been obtained. In the absence of model mismatch, de...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Korea Academia-Industrial cooperation Society
سال: 2010
ISSN: 1975-4701
DOI: 10.5762/kais.2010.11.4.1348